Homogeneous Catalysis with Renewables
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Introduction (Advantages of homogeneous catalysis in derivatisation of renewables).- Oleochemicals.- Reactions of fatty acids and derivatives.- Reactions on the carboxyl group (Hydrogenations, aminations etc.).- Reactions on the alkyl (alkenyl) chain (Self- and cross metathesis, Diels-Alder-Reaction, selective hydrogenation, oxidation, epoxidation, bis-hydroxylation, (isomerising) hydroformylation, carbonylation, hydroaminomethylation, hydro-carboxylation, (isomerising) hydroesterification, oligomerisation and co-oligo-merisation, cyclisation, polymerisation, hydrosilylation, etc.).- Reactions of glycerol (Esterification, etherification, dimerisation, telomerisation, ketalisation, acetalization, reduction, oxidation, dehydration etc.).- Isoprenoids (Terpenes and steroids).- Reactions of low-molecular terpenes (Rearrangements, hydrohalogenation, esterification, alkoxylation, hydration, Diels-Al¬der-reactions, oxidation, epoxidation, metathesis, hydroamination, hydroformyla¬tion, hydrosilylation, dimerisation, co-oligomerisation, telomerisation, polymerisation etc.).- Reactions of polyprenes / rubbers (hydroformylation, metathesis, etc.).- Carbohydrates.- Functionalisation of mono- and disaccharides (e.g. telomerisations).- Functionalisation of polysaccharides (cellulose, starch, hemicelluloses, chitin).- Lignin and lignin model compounds e.g. functionalisations and oxidations.- Proteins and amino acids.- Carbon dioxide, e.g. hydrogenations, telomerisations etc.
Written by highly cited authors
Aimed at researchers in academia and industry alike
Includes supplementary material: sn.pub/extras
Publications:
- U. Onken, A. Behr, Chemische Prozesskunde, Lehrbuch der Technischen Chemie Band 3, Georg Thieme Verlag Stuttgart/New York, 1996
- M. Baerns, A. Behr, A. Brehm, J. Gmehling, H. Hofmann, U. Onken, A. Renken, Technische Chemie, Wiley-VCH, Weinheim, 1. Ed. 2006
- A. Behr, Angewandte homogene Katalyse, Wiley-VCH, Weinheim, 2008
- A. Behr, D. W. Agar, J. Jörissen, Einführung in die Technische Chemie, Spektrum Akademischer Verlag, Heidelberg, 2010
- A. Behr, P. Neubert, Applied Homogeneous Catalysis, Wiley-VCH, Weinheim, 2012
- M. Baerns, A. Behr, A. Brehm, J. Gmehling, O. Hinrichsen, U. Onken, R. Palkovits, A. Renken, Technische Chemie, Wiley-VCH, Weinheim, 2. Ed. 2013
- A. Behr, Einführung in die Chemie nachwachsender Rohstoffe, Spektrum Akademi-scher Verlag, Heidelberg, (in preparation)
Dr. Vorholt: Ass. Prof. on the Chair of Technical Chemistry at TU Dortmund.
Publications:
- Contribution "Hydroformylation and Related Reactions of Renewable Resources" (A. Behr and A. J. Vorholt) in: Topics in Organometallic Chemistry, Eds.: M. A. R. Meier. B. M. Weckhuysen, P. C. A. Bruijnincx, Springer / Heidelberg, Vol. 39 (2012), 103-128
- Contribution “Oleochemistry” (A. Behr, A. J. Vorholt), in: Applied Homogeneous Catalysis with Organometallic Compounds, Eds.: B. Cornils, W. A. Herrmann, M. Beller, R. Paciello, Wiley-VCH, Weinheim, 2013 (in print)